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Kerala PSC General Science Book Study Materials Page 264
Book's First PagePauli Exclusion Principle Hund"s Rule It states that, in an atom or molecule, no two It states that, (1) Every orbital in a sublevel is electrons can have the same four electronic singly occupied before any orbital is doubly quantum numbers. As an orbital can contain a occupied. (2) All of the electrons in singly maximum of only two electrons, the two occupied orbitals have the same spin (to electrons must have opposing spins. This maximize total spin). means if one is assigned an up-spin (+1/2), the other must be down-spin (-1/2). Aufbau Principle : “to build” principle Electrons in the same orbital have the same It states that no two fermions (e.g., electrons) first three quantum numbers, e.g., n = 1, l = 0, in an atom can have the same set of quantum ml = 0 for the 1s subshell. Only two electrons numbers, hence they have to "pile up" or can have these numbers, so that their spin "build up" into higher energy levels. It means moments must be either ms = −1/2 or ms =+ electrons are added to orbitals as protons are 1/2. added to an atom. NUCLEAR CHEMISTRY Radioactivity The atomic number and mass depends upon the type of radioactive rays emitted Atoms become unstable due to large during nuclear reaction. The decay of neutron to proton ratio. Such unstable radioactive parent nuclei to stable nuclei is nucleus emitted some radiations and known as radioactive decay or nuclear convert in to some other stable nucleus decay. and known as radioactive elements. These The type of decay depends on the type of radiations are termed as radioactive rays. radioactive particles emitted in decay. For The property of emission of radioactive example, Alpha decay, Beta decay and rays from radioactive elements is termed Gamma decay. as radioactivity. It was discovered by Henry Becquerel in 1896. Generally, elements with atomic number more than 82 show radioactivity and disintegrated to small nuclei with the emission of alpha, beta, proton, neutron particles or gamma rays. This nuclei with decomposed is called as parent nuclei and the product nuclei is termed as daughter nuclei. Nuclear Radiation Name Charge Symbol Shield Distance traveled alpha positive (2He4)2+ or α paper or clothing 2-4 cm 0 beta negative -1e or β aluminum 2-3 m gamma neutral γ lead or concrete 500 m 263